Phosphorus triiodide photograph

Phosphorus Triiodide

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FormulaPI3
Molar mass411. 6872 g/mol
Boiling point200 °C
Molecular shapeTrigonal pyramidal
NFPA 704 (fire diamond)0 3 2
Solubility in waterDecomposes
Date of Reg.
Date of Upd.
ID3110719
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About Phosphorus Triiodide


Phosphorus triiodide is an unstable red solid which reacts violently with water. It is a common misconception that PI₃ is too unstable to be stored; it is, in fact, commercially available. It is widely used in organic chemistry for converting alcohols to alkyl iodides. It is also a powerful reducing agent.

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